Atypical photomagnetic properties in a series of binuclear iron(II) spin crossover complexes
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASTANET, Guillaume | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CARBONERA, Chiara | |
hal.structure.identifier | Interactions moléculaires et réactivité chimique et photochimique [IMRCP] | |
dc.contributor.author | MINGOTAUD, Christophe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
dc.date.issued | 2004 | |
dc.identifier.issn | 0959-9428 | |
dc.description.abstractEn | In this work, we have re-examined the photomagnetic properties of a series of binuclear iron(II) complexes of formula [{Fe(L)(NCX)2}2bpym], where L is bpym = 2,2-bipyrimidine and bt = 2,2-bithiazoline and X = S, Se, by light irradiation at 647.1–676.4 nm and at 830 nm and we confirm that after optical excitation the magnetic behaviors of [{Fe(bpym)(NCSe)2}2bpym](2), [{Fe(bt)(NCS)2}2bpym](3) and [{Fe(bt)(NCSe)2}2bpym](4) are close to the antiferromagnetic response of [{Fe(bpym)(NCS)2}2bpym](1) characterized by two iron(II) metal ions in the HS electronic configuration... | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.subject.en | Antiferromagnetic exchange | |
dc.subject.en | Energy level excitation | |
dc.subject.en | IR spectra | |
dc.subject.en | Magnetic relaxation | |
dc.subject.en | Magnetic susceptibility | |
dc.subject.en | Iron complex | |
dc.title.en | Atypical photomagnetic properties in a series of binuclear iron(II) spin crossover complexes | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/b408079c | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Materials Chemistry | |
bordeaux.page | 3516-3523 | |
bordeaux.volume | 14 | |
bordeaux.issue | 24 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00156585 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00156585v1 | |
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