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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARBONERA, Chiara
hal.structure.identifierInteractions moléculaires et réactivité chimique et photochimique [IMRCP]
dc.contributor.authorMINGOTAUD, Christophe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2004
dc.identifier.issn0959-9428
dc.description.abstractEnIn this work, we have re-examined the photomagnetic properties of a series of binuclear iron(II) complexes of formula [{Fe(L)(NCX)2}2bpym], where L is bpym = 2,2-bipyrimidine and bt = 2,2-bithiazoline and X = S, Se, by light irradiation at 647.1–676.4 nm and at 830 nm and we confirm that after optical excitation the magnetic behaviors of [{Fe(bpym)(NCSe)2}2bpym](2), [{Fe(bt)(NCS)2}2bpym](3) and [{Fe(bt)(NCSe)2}2bpym](4) are close to the antiferromagnetic response of [{Fe(bpym)(NCS)2}2bpym](1) characterized by two iron(II) metal ions in the HS electronic configuration...
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enAntiferromagnetic exchange
dc.subject.enEnergy level excitation
dc.subject.enIR spectra
dc.subject.enMagnetic relaxation
dc.subject.enMagnetic susceptibility
dc.subject.enIron complex
dc.title.enAtypical photomagnetic properties in a series of binuclear iron(II) spin crossover complexes
dc.typeArticle de revue
dc.identifier.doi10.1039/b408079c
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Materials Chemistry
bordeaux.page3516-3523
bordeaux.volume14
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-00156585
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00156585v1
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