Bi- and trinuclear copper(II) complexes of a sterically constrained phenol-based tetradentate ligand: syntheses, structures, and magnetic studies
| hal.structure.identifier | Department of Inorganic Chemistry | |
| dc.contributor.author | MUKHOPADHYAY, Suman | |
| hal.structure.identifier | Department of Inorganic Chemistry | |
| dc.contributor.author | MANDAL, Debdas | |
| hal.structure.identifier | Department of Inorganic Chemistry | |
| dc.contributor.author | BARAN CHATTERJEE, Pabitra | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | SUTTER, Jean-Pascal | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | BUTCHER, Ray J. | |
| hal.structure.identifier | Department of Inorganic Chemistry | |
| dc.contributor.author | CHAUDHURY, Muktimoy | |
| dc.date.issued | 2004 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | Cu(II) complexes of a sterically constrained phenol-based tetradentate N2O2 ligand 1,4-bis(2-hydroxy-3,5-dimethylbenzyl)piperazine (H2L) are reported. The assocd. anions of the Cu(II) ion precursors have profound influence on the stoichiometry of the products. Thus, with perchlorate ion, the product is binuclear [Cu2L2] (1), while with coordinating anions viz. Cl- and N3-, [Cu3L2Cl2(H2O)]×0.5H2L (2) and [Cu3L2(N3)2(MeOH)]×4H2O (3) have triangulo trinuclear compn. The syntheses, x-ray structures, and spectroscopic and magnetic properties of these complexes are described... | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Ferromagnetic exchange | |
| dc.subject.en | Antiferromagnetic exchange | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Molecular structure | |
| dc.subject.en | Copper hydroxydimethylbenzylpiperazine | |
| dc.title.en | Bi- and trinuclear copper(II) complexes of a sterically constrained phenol-based tetradentate ligand: syntheses, structures, and magnetic studies | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ic049271r | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 8501-8509 | |
| bordeaux.volume | 43 | |
| bordeaux.issue | 26 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00157927 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00157927v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2004&rft.volume=43&rft.issue=26&rft.spage=8501-8509&rft.epage=8501-8509&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=MUKHOPADHYAY,%20Suman&MANDAL,%20Debdas&BARAN%20CHATTERJEE,%20Pabitra&DESPLANCHES,%20C%C3%A9dric&SUTTER,%20Jean-Pascal&rft.genre=article |
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