Synthesis of Five Generations of Redox-Stable Pentamethylamidoferrocenyl Dendrimers and Comparison of Amidoferrocenyl- and Pentamethylamidoferrocenyl Dendrimers as Electrochemical Exoreceptors for the Selective Recognition of H2PO4-, HSO4-, and Adenosine 5-Triphosphate (ATP) Anions: Stereoelectronic and Hydrophobic Roles of Cyclopentadienyl Permethylation
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en
Article de revue
Este ítem está publicado en
Chemistry - A European Journal. 2003, vol. 9, n° 18, p. 4371-4379
Wiley-VCH Verlag
Resumen en inglés
A family of five metallodendrimers with pentamethylamidoferrocenyl termini were synthesized from the DSM dendrimers Gn-DAB-dend-(NH2)x (x=4, 8, 16, 32, 64) and characterized by standard techniques, including prominent ...Leer más >
A family of five metallodendrimers with pentamethylamidoferrocenyl termini were synthesized from the DSM dendrimers Gn-DAB-dend-(NH2)x (x=4, 8, 16, 32, 64) and characterized by standard techniques, including prominent molecular peaks (broad for x=64) in their MALDI-TOF mass spectra. Oxidation of G4-DAB-dend-(NHCOFc*)x...< Leer menos
Palabras clave en italiano
Cyclic voltammetry
Dendrimers
Metallocenes
Molecular recognition
Receptors
Orígen
Importado de HalCentros de investigación