YADNUM, Sudarat; ROCHE, Jérome; LEBRAUD, Eric; NÉGRIER, Philippe; GARRIGUE, Patrick; BRADSHAW, Darren; WARAKULWIT, Chompunuch; LIMTRAKUL, Jumras; KUHN, Alexander

doi:10.1002/anie.201400581

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Licencia de uso del documento

http://creativecommons.org/licenses/by-nc/

YADNUM, Sudarat
Institut des Sciences Moléculaires [ISM]
Department of Chemistry [Bangkok]

ROCHE, Jérome
Institut des Sciences Moléculaires [ISM]

LEBRAUD, Eric
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Article de revue

Este ítem está publicado en

Angewandte Chemie International Edition. 2014-04-07, vol. 53, n° 15, p. 4001-4005

Wiley-VCH Verlag

Resumen en inglés

Herein, bipolar electrochemistry is applied in a straightforward way to the site-selective in situ synthesis of metal-organic framework (MOF) structures, which have attracted tremendous interest in recent years because of their significant application potential, ranging from sensing to gas storage and catalysis. The novelty of the presented work is that the deposit can be intentionally confined to a defined area of a substrate without using masks or templates. The intrinsic site-selectivity of bipolar electrochemistry makes it a method of choice to generate, in a highly controlled way, hybrid particles that may have different functionalities combined on the same particle. The wireless nature of electrodeposition allows the potential for mass production of such Janus-type objects.< Leer menos

Palabras clave en inglés

Metal-organic frameworks

Composites

Electrochemistry

Electrocrystallization

Janus particles

DOI

http://dx.doi.org/10.1002/anie.201400581

Proyecto europeo

Biomineral-inspired growth and processing of metal-organic frameworks

Proyecto ANR

Procédé de production de particules dissymétriques par électrochimie bipolaire - ANR-11-EMMA-0007

Orígen

Importado de Hal

Centros de investigación

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026