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Intercalation polymerization

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDUGUET, Etienne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorREY, Stéphanie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMÉRIDA-ROBLES, Josepha Maria
dc.contributor.editorHerman F. Mark
dc.date.issued2007
dc.identifier.isbn0-470-04610-4
dc.description.abstractEnPolymer-layered nanocomposites are made of the alternation of inorganic slabs and polymer layers. They may be obtained through (1) the synthesis of the mineral slabs from soluble precursors in a macromolecular solution, (2) mineral slab exfoliation and their subsequent restacking after adsorption of macromolecules (encapsulative precipitation), (3) the direct intercalation of macromolecules in the interslab space, (4) the intercalation of monomer molecules and their in situ simultaneous or subsequent polymerization. In this article, the main layered inorganic lattices, which readily undergo intercalation reaction, and the corresponding intercalation driving forces are described. The synthesis of polymer-layered nanocomposites are presented essentially from the viewpoint of the polymer chemist. The polymerization mechanisms, the molecular weight distribution, and the interslab arrangement of the intercalated macromolecules are discussed. Among the original properties of such polymer-layered nanocomposites, a special emphasis is made on their enhanced ionic or electron conductivity and their thermal stability.
dc.language.isoen
dc.publisher.locationHoboken (N. J.)
dc.source.titleEncyclopedia of Polymer Science and Technology
dc.title.enIntercalation polymerization
dc.typeChapitre d'ouvrage
dc.subject.halChimie/Matériaux
bordeaux.page590-593
bordeaux.title.proceedingEncyclopedia of Polymer Science and Technology
hal.identifierhal-00176534
hal.version1
hal.popularnon
hal.audienceNon spécifiée
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00176534v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.btitle=Encyclopedia%20of%20Polymer%20Science%20and%20Technology&rft.date=2007&rft.spage=590-593&rft.epage=590-593&rft.au=DUGUET,%20Etienne&REY,%20St%C3%A9phanie&M%C3%89RIDA-ROBLES,%20Josepha%20Maria&rft.isbn=0-470-04610-4&rft.genre=unknown


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