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hal.structure.identifierLaboratoire de Chimie Structurale des Matériaux, Département de Chimie
dc.contributor.authorHIDOURI, Mourad
hal.structure.identifierLaboratoire de Chimie Structurale des Matériaux, Département de Chimie
dc.contributor.authorLAJMI, Besma
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorWATTIAUX, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFOURNÈS, Léopold
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARRIET, Jacques
hal.structure.identifierLaboratoire de Chimie Structurale des Matériaux, Département de Chimie
dc.contributor.authorBEN AMARA, Mongi
dc.date.issued2003
dc.identifier.issn0925-8388
dc.description.abstractEnA new sodium and calcium iron phosphate, NaCaFe3(PO4)4, has been synthesized by a flux method and characterized by single crystal X-ray diffraction, magnetic susceptibility and Mössbauer spectroscopy. The compound crystallizes in the orthorhombic space group Pcab with the parameters a=8.706(4) Å, b=9.410(1) Å, c=29.211(6) Å, V=2393 Å3 and Z=8. The structure consists of discrete FeO6 octahedra and FeO5 trigonal bipyramids, corner-sharing with PO4 tetrahedra that form a [Fe3P4O16]n three-dimensional framework with two distinct cavities which are the Na+ and Ca2+ sites. Mössbauer spectroscopy results confirm those obtained from X-ray diffraction...
dc.language.isoen
dc.publisherElsevier
dc.subject.enTransition metal compounds
dc.subject.enChemical synthesis
dc.subject.enCrystal structure
dc.subject.enMagnetic measurements
dc.subject.enMössbauer spectroscopy
dc.title.enCrystal structure, magnetic properties and Mössbauer spectroscopy of NaCaFe3(PO4)4
dc.typeArticle de revue
dc.identifier.doi10.1016/S0925-8388(03)00129-4
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Alloys and Compounds
bordeaux.page36-41
bordeaux.volume358
bordeaux.issue1-2
bordeaux.peerReviewedoui
hal.identifierhal-00180123
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00180123v1
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