Crystal structure, magnetic properties and Mössbauer spectroscopy of NaCaFe3(PO4)4
hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
dc.contributor.author | HIDOURI, Mourad | |
hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
dc.contributor.author | LAJMI, Besma | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | WATTIAUX, Alain | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | FOURNÈS, Léopold | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DARRIET, Jacques | |
hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
dc.contributor.author | BEN AMARA, Mongi | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0925-8388 | |
dc.description.abstractEn | A new sodium and calcium iron phosphate, NaCaFe3(PO4)4, has been synthesized by a flux method and characterized by single crystal X-ray diffraction, magnetic susceptibility and Mössbauer spectroscopy. The compound crystallizes in the orthorhombic space group Pcab with the parameters a=8.706(4) Å, b=9.410(1) Å, c=29.211(6) Å, V=2393 Å3 and Z=8. The structure consists of discrete FeO6 octahedra and FeO5 trigonal bipyramids, corner-sharing with PO4 tetrahedra that form a [Fe3P4O16]n three-dimensional framework with two distinct cavities which are the Na+ and Ca2+ sites. Mössbauer spectroscopy results confirm those obtained from X-ray diffraction... | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Transition metal compounds | |
dc.subject.en | Chemical synthesis | |
dc.subject.en | Crystal structure | |
dc.subject.en | Magnetic measurements | |
dc.subject.en | Mössbauer spectroscopy | |
dc.title.en | Crystal structure, magnetic properties and Mössbauer spectroscopy of NaCaFe3(PO4)4 | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/S0925-8388(03)00129-4 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Alloys and Compounds | |
bordeaux.page | 36-41 | |
bordeaux.volume | 358 | |
bordeaux.issue | 1-2 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00180123 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00180123v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Alloys%20and%20Compounds&rft.date=2003&rft.volume=358&rft.issue=1-2&rft.spage=36-41&rft.epage=36-41&rft.eissn=0925-8388&rft.issn=0925-8388&rft.au=HIDOURI,%20Mourad&LAJMI,%20Besma&WATTIAUX,%20Alain&FOURN%C3%88S,%20L%C3%A9opold&DARRIET,%20Jacques&rft.genre=article |
Files in this item
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |