HIDOURI, Mourad; LAJMI, Besma; WATTIAUX, Alain; FOURNÈS, Léopold; DARRIET, Jacques; BEN AMARA, Mongi

doi:10.1016/S0925-8388(03)00129-4

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

HIDOURI, Mourad
Laboratoire de Chimie Structurale des Matériaux, Département de Chimie

LAJMI, Besma
Laboratoire de Chimie Structurale des Matériaux, Département de Chimie

WATTIAUX, Alain
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

Idioma

Article de revue

Este ítem está publicado en

Journal of Alloys and Compounds. 2003, vol. 358, n° 1-2, p. 36-41

Elsevier

Resumen en inglés

A new sodium and calcium iron phosphate, NaCaFe3(PO4)4, has been synthesized by a flux method and characterized by single crystal X-ray diffraction, magnetic susceptibility and Mössbauer spectroscopy. The compound crystallizes in the orthorhombic space group Pcab with the parameters a=8.706(4) Å, b=9.410(1) Å, c=29.211(6) Å, V=2393 Å3 and Z=8. The structure consists of discrete FeO6 octahedra and FeO5 trigonal bipyramids, corner-sharing with PO4 tetrahedra that form a [Fe3P4O16]n three-dimensional framework with two distinct cavities which are the Na+ and Ca2+ sites. Mössbauer spectroscopy results confirm those obtained from X-ray diffraction...< Leer menos

Palabras clave en inglés

Transition metal compounds

Chemical synthesis

Crystal structure

Magnetic measurements

Mössbauer spectroscopy

Metadatos

Licencia de uso del documento

Crystal structure, magnetic properties and Mössbauer spectroscopy of NaCaFe3(PO4)4

Idioma

Este ítem está publicado en

Resumen en inglés

Palabras clave en inglés

DOI

Orígen

Centros de investigación