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hal.structure.identifierCentre for Materials Crystallography
dc.contributor.authorBROGE, Nils Lau Nyborg
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPHILIPPOT, Gilles
hal.structure.identifierCentre for Materials Crystallography
dc.contributor.authorIVERSEN, Bo Brummerstedt
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorAYMONIER, Cyril
dc.date.issued2018
dc.identifier.issn1477-9226
dc.description.abstractEnSynthesis of phase pure hopeite pigment through a solvothermal flow method is reported here for the first time. The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing the reaction temperature stepwise from room temperature to 350 °C it was possible to decrease the size of the individual crystallite sheets and to tune their packing into larger assemblies. The conversion of reactants to product proved to be significantly higher at increased temperature with a measured yield of 98.7% at 250 °C versus 85.4% at room temperature. The synthesis route demonstrated here is environmentally sustainable, increases cost-efficiency through minimization of waste, and is compatible with a scale-up strategy.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enSolvothermal flow synthesis of zinc phosphate pigment
dc.typeArticle de revue
dc.subject.halChimie/Matériaux
bordeaux.journalDalton Transactions
bordeaux.page9136-9142
bordeaux.volume47
bordeaux.issue27
bordeaux.peerReviewedoui
hal.identifierhal-01845499
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01845499v1
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