Nanoporous magnets of chiral and racemic [{Mn(HL)}2Mn{Mo(CN)7}2] with switchable ordering temperatures (TC = 85 K 106 K) driven by H2O sorption (L = N,N-dimethylalaninol)
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | MILON, Julie | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DANIEL, Marie-Christine | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon] [ICMUB] | |
| dc.contributor.author | BRANDÈS, Stéphane | |
| hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
| dc.contributor.author | SUTTER, Jean-Pascal | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0002-7863 | |
| dc.description.abstractEn | Molecule-based solids represent a rare opportunity to combine, adjust, and interrelate structural and physical functionalities to develop multifunctional materials. Here we report on a series of porous supramolecular magnets whose magnetic properties are related to their sorption state. A family of magnets of the formula [{Mn(HL)(H2O)}2Mn{Mo(CN)7}2]·2H2O have been obtained by assembling the heptacyano-metalate building unit {Mo(CN)7}4- with Mn(II) in the presence of protonated N,N-dimethylalaninol (L) as ligand, the latter being either as a racemic mixture or as a chiral R- or S-enantiomer... | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Nanoporous materials | |
| dc.subject.en | Supramolecular magnet | |
| dc.subject.en | Sorption state | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Chemical compounds | |
| dc.title.en | Nanoporous magnets of chiral and racemic [{Mn(HL)}2Mn{Mo(CN)7}2] with switchable ordering temperatures (TC = 85 K 106 K) driven by H2O sorption (L = N,N-dimethylalaninol) | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ja073612t | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of the American Chemical Society | |
| bordeaux.page | 13872-13878 | |
| bordeaux.volume | 129 | |
| bordeaux.issue | 45 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00186370 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00186370v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.date=2007&rft.volume=129&rft.issue=45&rft.spage=13872-13878&rft.epage=13872-13878&rft.eissn=0002-7863&rft.issn=0002-7863&rft.au=MILON,%20Julie&DANIEL,%20Marie-Christine&KAIBA,%20Abdellah&GUIONNEAU,%20Philippe&BRAND%C3%88S,%20St%C3%A9phane&rft.genre=article |
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