Synthesis, structure and characterisation of Fe0.50Ti2(PO4)3: A new material with Nasicon-like structure
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | BENMOKHTAR, Saïd | |
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | EL JAZOULI, Abdelaziz | |
| hal.structure.identifier | Laboratoire de Chimie des Matériaux Solides | |
| dc.contributor.author | AATIQ, A. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHAMINADE, Jean-Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRAVEREAU, Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | WATTIAUX, Alain | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | FOURNÈS, Léopold | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRENIER, Jean-Claude | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0022-4596 | |
| dc.description.abstractEn | A new iron titanyl phosphate Fe0.50Ti2(PO4)3 was synthesized by both solid-state reaction and Cu2+–Fe2+ ion exchange method. The material was then characterized by X-ray diffraction, Mössbauer, magnetic susceptibility measurements and optical absorption. The crystal structure of the compound was refined, using X-ray powder diffraction data, by the Rietveld profile method; it crystallizes in the rhombohedral system, space group Click to view the MathML source, with a=8.511(1) Å and c=20.985(3) Å, V=1316.45(3) Å3 and Z=6. The structure, which is compared to that of Mn0.50Ti2(PO4)3 is built up from [TiO6] octahedra and [PO4] tetrahedra which are linked by corner sharing along the c-axis. Fe2+ cations are located in half of the antiprism MI sites and are orderly distributed with vacancies within the two possible positions of the MI sites of ... | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Synthesis | |
| dc.subject.en | Phosphate | |
| dc.subject.en | Nasicon | |
| dc.subject.en | X-ray diffraction | |
| dc.subject.en | Mössbauer spectroscopy | |
| dc.subject.en | Magnetic measurements | |
| dc.subject.en | UV–visible | |
| dc.title.en | Synthesis, structure and characterisation of Fe0.50Ti2(PO4)3: A new material with Nasicon-like structure | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jssc.2007.04.014 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Solid State Chemistry | |
| bordeaux.page | 2004-2012 | |
| bordeaux.volume | 180 | |
| bordeaux.issue | 7 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00187799 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00187799v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Solid%20State%20Chemistry&rft.date=2007&rft.volume=180&rft.issue=7&rft.spage=2004-2012&rft.epage=2004-2012&rft.eissn=0022-4596&rft.issn=0022-4596&rft.au=BENMOKHTAR,%20Sa%C3%AFd&EL%20JAZOULI,%20Abdelaziz&AATIQ,%20A.&CHAMINADE,%20Jean-Pierre&GRAVEREAU,%20Pierre&rft.genre=article |
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