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hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROUET, Pierre-Etienne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHOMETTE, Cyril
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorADUMEAU, Laurent
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDUGUET, Etienne
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorRAVAINE, Serge
dc.date.issued2018
dc.identifier.issn2190-4286
dc.description.abstractEnWe report a new route to synthesize clusters, or so-called colloidal molecules (CMs), which mimic the symmetry of molecular structures made of one central atom. We couple site-specifically functionalized patchy nanoparticles, i.e., valence-endowed colloidal atoms (CAs), with complementary nanospheres through amide bonds. By analogy with the Gillespie formalism, we show that AX4, AX3E1 and AX2E2 CMs can be obtained from tetravalent sp3-like CAs when the relative amount of both building units is varied in a controlled manner. We obtain AX2 CMs from divalent sp-like CAs. We also show that it is possible to covalently attach two different types of satellites to the same central patchy nanoparticle to create more complex CMs, opening the way to the fabrication of new multifunctional nanostructures with well-controlled shape and composition.
dc.description.sponsorshipDilater le système atomique conventionnel à l'échelle colloïdale grâce à des particules préprogrammées pour une valence donnée - ANR-15-CE09-0010
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
dc.language.isoen
dc.publisherKarlsruhe Institute of Technology.
dc.subject.encolloidal molecules
dc.subject.encovalent bonding
dc.subject.enpatchy nanoparticles
dc.subject.envalence
dc.title.enColloidal chemistry with patchy silica nanoparticles
dc.typeArticle de revue
dc.identifier.doi10.3762/bjnano.9.278
dc.subject.halChimie/Matériaux
bordeaux.journalBeilstein Journal of Nanotechnology
bordeaux.page2989-2998
bordeaux.volume9
bordeaux.peerReviewedoui
hal.identifierhal-01952391
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01952391v1
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