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hal.structure.identifierInstitut de la matière condensée et des nanosciences / Institute of Condensed Matter and Nanosciences [IMCN]
dc.contributor.authorADARSH, Nayarassery
hal.structure.identifierInstitut de la matière condensée et des nanosciences / Institute of Condensed Matter and Nanosciences [IMCN]
dc.contributor.authorDÎRTU, Marinela
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInstitute of Nanoscience and Nanotechnology
dc.contributor.authorDEVLIN, Eamonn
hal.structure.identifierInstitute of Nanoscience and Nanotechnology
dc.contributor.authorSANAKIS, Yiannis
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorHOWARD, Judith
hal.structure.identifierDepartment of Physics [Trondheim] [Physics NTNU]
dc.contributor.authorCHATTOPADHYAY, Basab
hal.structure.identifierInstitut de la matière condensée et des nanosciences / Institute of Condensed Matter and Nanosciences [IMCN]
dc.contributor.authorGARCIA, Yann
dc.date.issued2019
dc.identifier.issn1434-1948
dc.description.abstractEnTwo new coordination polymers [Cu(btzx)2(MeOH)2](NO3)2 (1) and [Cu(btrcy)2(H2O)2](ClO4)2·btrcy (2) have been synthesized by reacting two bis‐triazole/tetrazole‐ligands namely m‐xylylene‐bis(tetrazole) (btzx) and bis(1,2,4‐triazole)‐trans‐cyclohexane (btrcy) with Cu(NO3)2 and Cu(ClO4)2 respectively in a 1:3 metal/ligand ratio. These compounds are shown to form X‐ray quality single‐crystals under different conditions, and the crystal structures have been determined by single‐crystal X‐ray diffraction (SXRD). The SXRD data analysis revealed that 1 and 2 are 1D looped chain and 2D‐square grid coordination polymers, respectively. More interestingly, the 2D‐square grid architecture in 2 acts as an excellent host for the large guest ligand molecule btrcy, which is encapsulated within the voids of the 2D coordination polymer.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enOne‐dimensional looped chain and two‐dimensional square grid coordination polymers: encapsulation of bis(1,2,4‐triazole)‐trans‐cyclohexane into the voids
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.201801138
dc.subject.halChimie/Matériaux
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page585-591
bordeaux.issue5
bordeaux.peerReviewedoui
hal.identifierhal-02025734
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02025734v1
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