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Effect of solvent on silicon nanoparticle formation and size: a mechanistic study

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSEMLALI, Sanaa
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCORMARY, Benoit
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDE MARCO, Maria
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAJIMEL, Jérôme
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSOURNIA-SAQUET, Alix
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorCOPPEL, Yannick
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGONIDEC, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDRISKO, Glenna
dc.date.issued2019-03-14
dc.identifier.issn2040-3364
dc.description.abstractEnSilicon has emerged as the most desirable material for optical dielectric metamaterials, however chemists struggle to obtain the required silicon nanoparticle dimensions. Here the average diameter of silicon nanoparticles is varied between 3 and 15 nm by changing the reaction solvent. Electrochemistry and NMR elucidate the role of solvent on the synthetic mechanism. Surprisingly the solvent does not stabilize the nanoparticles and there is no trend associated with chain length or open-chain versus cyclical solvent molecules. The solvent's main role is to stabilize the by-products, which prolongs the reaction lifetime.
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enEffect of solvent on silicon nanoparticle formation and size: a mechanistic study
dc.typeArticle de revue
dc.identifier.doi10.1039/C9NR00619B
dc.subject.halChimie/Matériaux
bordeaux.journalNanoscale
bordeaux.page4696-4700
bordeaux.volume11
bordeaux.issue11
bordeaux.peerReviewedoui
hal.identifierhal-02071674
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02071674v1
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