SEMLALI, Sanaa; CORMARY, Benoit; DE MARCO, Maria; MAJIMEL, Jérôme; SOURNIA-SAQUET, Alix; COPPEL, Yannick; GONIDEC, Mathieu; ROSA, Patrick; DRISKO, Glenna

doi:10.1039/C9NR00619B

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SEMLALI, Sanaa
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

CORMARY, Benoit
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DE MARCO, Maria
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Nanoscale. 2019-03-14, vol. 11, n° 11, p. 4696-4700

Royal Society of Chemistry

Resumen en inglés

Silicon has emerged as the most desirable material for optical dielectric metamaterials, however chemists struggle to obtain the required silicon nanoparticle dimensions. Here the average diameter of silicon nanoparticles is varied between 3 and 15 nm by changing the reaction solvent. Electrochemistry and NMR elucidate the role of solvent on the synthetic mechanism. Surprisingly the solvent does not stabilize the nanoparticles and there is no trend associated with chain length or open-chain versus cyclical solvent molecules. The solvent's main role is to stabilize the by-products, which prolongs the reaction lifetime.< Leer menos

DOI

http://dx.doi.org/10.1039/C9NR00619B

Proyecto ANR

Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003

Orígen

Importado de Hal

Centros de investigación

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026