Green coloration of Co-doped ZnO explained from structural refinement and bond considerations
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GAUDON, Manuel | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | TOULEMONDE, Olivier | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DEMOURGUES, Alain | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0020-1669 | |
dc.description.abstractEn | ZnO doped with Co2+ has been prepared by a Pechini process and investigated in terms of crystallographic structure and UV-visible properties. We emphasize for the first time a splitting of the ZnO band gap in two "sub-band gaps" (never clearly mentioned until now) which is fully interpreted basing on the iono-covalent nature of the O-Zn bonds. An anticipative approach of the potential structure relaxations was discussed from exchanged effective charge per bond calculated with the purely ionic Brown and Altermatt model. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Electric charge | |
dc.subject.en | Color | |
dc.subject.en | UV and visible spectra | |
dc.subject.en | Bond length | |
dc.subject.en | Band gap | |
dc.subject.en | Zinc oxide | |
dc.subject.en | Cobalt(2+) | |
dc.title.en | Green coloration of Co-doped ZnO explained from structural refinement and bond considerations | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/ic701157j | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Inorganic Chemistry | |
bordeaux.page | 10996-11002 | |
bordeaux.volume | 46 | |
bordeaux.issue | 26 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00229843 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00229843v1 | |
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