First crystallographic evidence for the formation of β-Image-ribopyranosylamine from the reaction of ammonia with of Image-ribose
Language
en
Article de revue
This item was published in
Carbohydrate Research. 2003, vol. 338, n° 8, p. 801-805
Elsevier
English Abstract
β-d-Ribopyranosylamine was synthesized and characterized using analytical, spectral and single-crystal X-ray diffraction methods. The molecule exists in the chair form with the 4C1 conformation. The β anomeric form of C-1 ...Read more >
β-d-Ribopyranosylamine was synthesized and characterized using analytical, spectral and single-crystal X-ray diffraction methods. The molecule exists in the chair form with the 4C1 conformation. The β anomeric form of C-1 is supported by the dihedral angles. The molecule exhibits both intra- and intermolecular hydrogen-bond interactions of the type O---Hcdots, three dots, centeredO, N---Hcdots, three dots, centeredO and C---Hcdots, three dots, centeredO, and these are interconnected to each other to form chains.Read less <
English Keywords
D-Ribopyranosylamine
Single-crystal X-ray diffraction
Glycosyl amines
Origin
Hal imported