Solution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes
| hal.structure.identifier | MacDiarmid Institute for Advanced Materials and Nanotechnology | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | WILSON, Benjamin | |
| hal.structure.identifier | MacDiarmid Institute for Advanced Materials and Nanotechnology | |
| dc.contributor.author | SCOTT, Hayley | |
| hal.structure.identifier | MacDiarmid Institute for Advanced Materials and Nanotechnology | |
| dc.contributor.author | ARCHER, Rosanna | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | CLÉRAC, Rodolphe | |
| hal.structure.identifier | MacDiarmid Institute for Advanced Materials and Nanotechnology | |
| dc.contributor.author | KRUGER, Paul | |
| dc.date.issued | 2019-06 | |
| dc.identifier.issn | 2312-7481 | |
| dc.description.abstractEn | We report herein on five new Fe(II) complexes of general formula [Fe(L)2(NCCH3)2](BF4)2xCH3CN (L = substituted 2-pyridylimine-based ligands). The influence of proximally located electron withdrawing groups (e.g., NO2, CN, CF3, Cl, Br) bound to coordinated pyridylimine ligands has been studied for the effect on spin crossover in their Fe(II) complexes.Variable-temperature UV-visible spectroscopic studies performed on complexes with more strongly electronegative ligand substituents revealed spin crossover (SCO) in the solution, and thermodynamic parameters associated with the spin crossover were estimated. | |
| dc.language.iso | en | |
| dc.publisher | MDPI | |
| dc.subject.en | Fe(II) | |
| dc.title.en | Solution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.3390/magnetochemistry5020022 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Magnetochemistry | |
| bordeaux.page | 22 (13 p.) | |
| bordeaux.volume | 5 | |
| bordeaux.issue | 2 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02171591 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02171591v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Magnetochemistry&rft.date=2019-06&rft.volume=5&rft.issue=2&rft.spage=22%20(13%20p.)&rft.epage=22%20(13%20p.)&rft.eissn=2312-7481&rft.issn=2312-7481&rft.au=WILSON,%20Benjamin&SCOTT,%20Hayley&ARCHER,%20Rosanna&MATHONI%C3%88RE,%20Corine&CL%C3%89RAC,%20Rodolphe&rft.genre=article |
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