Show simple item record

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBALDÉ, Cherif
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorWATTIAUX, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInsitut für Anorganische und Analytische Chemie
dc.contributor.authorGÜTLICH, Philipp
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2008
dc.identifier.issn1477-9226
dc.description.abstractEnThe thermal and light-induced spin transitions in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenantholine) have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and undergo the light-induced excited spin state trapping (LIESST) effect at low temperatures. For each compound, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged. This behaviour is discussed on the basis of the kinetic study governing the photo-induced back conversion.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enLIESST
dc.subject.enMagnetic susceptibility
dc.subject.enPhotomagnetism
dc.subject.enDiffuse reflectivity measurements
dc.subject.enMetal
dc.subject.enChemical compounds
dc.title.enEffect of metal dilution on the light-induced spin transition in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenanthroline)
dc.typeArticle de revue
dc.identifier.doi10.1039/b800248g
dc.subject.halChimie/Matériaux
bordeaux.journalDalton Transactions
bordeaux.page2702-2707
bordeaux.issue20
bordeaux.peerReviewedoui
hal.identifierhal-00293412
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00293412v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2008&rft.issue=20&rft.spage=2702-2707&rft.epage=2702-2707&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=BALD%C3%89,%20Cherif&DESPLANCHES,%20C%C3%A9dric&WATTIAUX,%20Alain&GUIONNEAU,%20Philippe&G%C3%9CTLICH,%20Philipp&rft.genre=article


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record