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hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorCUCINOTTA, Giuseppe
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorPOGGINI, Lorenzo
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorGIACONI, Niccolò
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
hal.structure.identifierDipartimento di Fisica e Astronomia [Firenze]
dc.contributor.authorCINI, Alberto
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGONIDEC, Mathieu
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorATZORI, Matteo
hal.structure.identifierIstituto di Chimica dei Composti Organometallici [ICCOM]
dc.contributor.authorBERRETTI, Enrico
hal.structure.identifierIstituto di Chimica dei Composti Organometallici [ICCOM]
dc.contributor.authorLAVACCHI, Alessandro
hal.structure.identifierDipartimento di Fisica e Astronomia [Firenze]
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorFITTIPALDI, Maria
hal.structure.identifierEuropean Synchrotron Radiation Facility [ESRF]
dc.contributor.authorCHUMAKOV, Aleksandr I.
hal.structure.identifierEuropean Synchrotron Radiation Facility [ESRF]
dc.contributor.authorRÜFFER, Rudolf
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorMANNINI, Matteo
dc.date.issued2020
dc.identifier.issn1944-8244
dc.description.abstractEnSpin crossover complexes are among the most studied classes of molecular switches and have attracted considerable attention for their potential technological use as active units in multifunctional devices. A fundamental step toward their practical implementation is the integration in macroscopic devices adopting hybrid vertical architectures. First, the physical properties of technological interest shown by these materials in the bulk phase have to be retained once they are deposited on a solid surface. Herein, we describe the study of a hybrid molecular inorganic junction embedding the spin crossover complex [Fe(qnal)2] (qnal = quinoline-naphthaldehyde) as an active switchable thin film sandwiched within energy-optimized metallic electrodes. In these junctions, developed and characterized with the support of state of the art techniques including synchrotron Mössbauer source (SMS) spectroscopy and focused-ion beam scanning transmission electron microscopy, we observed that the spin state conversion of the Fe(II)-based spin crossover film is associated with a transition from a space charge-limited current (SCLC) transport mechanism with shallow traps to a SCLC mechanism characterized by the presence of an exponential distribution of traps concomitant with the spin transition temperature.
dc.language.isoen
dc.publisherWashington, D.C. : American Chemical Society
dc.subject.enSpin crossover
dc.subject.enTransport measurements
dc.subject.enHybrid device
dc.subject.enFIB-STEM
dc.subject.enSynchrotron Mössbauer spectroscopy
dc.subject.enMolecular magnetism
dc.subject.enMolecular spintronics
dc.title.enSpace charge-limited current transport mechanism in crossbar junction embedding molecular spin crossovers
dc.typeArticle de revue
dc.identifier.doi10.1021/acsami.0c07445
dc.subject.halChimie/Matériaux
bordeaux.journalACS Applied Materials & Interfaces
bordeaux.page31696-31705
bordeaux.volume12
bordeaux.issue28
bordeaux.peerReviewedoui
hal.identifierhal-02906236
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02906236v1
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