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hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorMEYRE, Marie-Edith
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTRÉGUER-DELAPIERRE, Mona
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorFAURE, Chrystel
dc.date.issued2008
dc.identifier.issn0743-7463
dc.description.abstractEnA sheared lamellar phase has been used as a nanoreactor for the synthesis of gold nanoparticles by radiolysis and by a photochemical approach. A gold salt solution (KAuCl4, 10-2 M) is introduced into the aqueous compartments between the lipid-based bilayers. Gold nanoparticles grow within the lamellar phase as shown by TEM analysis and X-ray diffraction, limiting the particle size. Homodisperse, 2.4- and 5.9-nm-sized, spherical nanoparticles are produced by irradiation and UV irradiation, respectively. When produced by radiolysis, they are perfectly aligned along the lamellae. Their UV-vis spectra display a maximum at 565 nm suggesting that nanoparticles are coupled by dipole-dipole interactions within the lamellar phase.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enGold
dc.subject.enChemical synthesis
dc.subject.enNanoparticles
dc.subject.enColloids
dc.title.enRadiation-induced synthesis of gold nanoparticles within lamellar Phases. Formation of aligned colloidal gold by radiolysis
dc.typeArticle de revue
dc.identifier.doi10.1021/la703650d
dc.subject.halChimie/Matériaux
bordeaux.journalLangmuir
bordeaux.page4421-4425
bordeaux.volume24
bordeaux.issue9
bordeaux.peerReviewedoui
hal.identifierhal-00300268
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00300268v1
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