Local Distortions in Nanostructured Ferroelectric Ceramics through Strain Tuning
Language
en
Article de revue
This item was published in
Advanced Electronic Materials. 2015, vol. 1, n° 10, p. 1500190 (8 p.)
Wiley
English Abstract
Ferroelectric materials are highly sensitive to grain size reduction because strain and ferroelectric polarization have a direct connection. Using 15 nm (Ba,Sr)TiO3 particles obtained by advanced supercritical synthesis ...Read more >
Ferroelectric materials are highly sensitive to grain size reduction because strain and ferroelectric polarization have a direct connection. Using 15 nm (Ba,Sr)TiO3 particles obtained by advanced supercritical synthesis and their densification by high-pressure spark plasma sintering under air, reproducible and dense nanostructured ceramics are achieved. Taking advantage of the high pressure (up to 600 MPa) applied during the sintering step, the internal stress generated at the grain scale can be monitored to compensate for the particle surface stress due to size effect. Both the local dynamics observed by Raman scattering and the overall dielectric behavior consistently indicate a recovery of the ferroelectric properties as the sintering pressure is increased. This unique behavior shows that low-temperature and high-pressure processing enables designing nanostructured functional ceramics exhibiting original properties.Read less <
English Keywords
dielectrics
nanostructures
structure–property relationships
ceramics
ANR Project
Corrélations entre Architecture, Interfaces et Fonctionnalités dans les multi-matériaux Ferroélectriques :Frittage Flash et caractérisations multi-échelle 3D
Origin
Hal imported