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Discussion on the Structure Stability and the Luminescence Switch under Irradiation of a Ce-Doped Elpasolite Compound.

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCORNU, Lucile
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGAUDON, Manuel
hal.structure.identifierCentre National de la Recherche Scientifique [CNRS]
hal.structure.identifierUniversitatea de Vest din Timișoara [România] = West University of Timișoara [Romania] = Université Ouest de Timișoara [Roumanie] [UVT]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVEBER, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVILLESUZANNE, Antoine
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPECHEV, Stanislav
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGARCIA, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJUBERA, Veronique
dc.date.issued2015
dc.identifier.issn0947-6539
dc.description.abstractEnCe-doped Rb2 KInF6 elpasolite has the potential for tunable luminescence due to an unusual reversible redox process between the cerium and indium cations. Coupled with a deep understanding of the luminescence properties, XRD analysis and DFT calculations are used to locate the doping elements in the host lattice. The origin explanation of the charge-transfer mechanism that causes a decrease or increase in the blue-green cerium emission in opposition to the red indium emission is discussed regarding the crystallographic structure, the connection of the metallic cations and their equilibrium valence. Still detectable after nineteen years, the optical contrast created under irradiation makes this material a good candidate as photosensor for data storage.
dc.description.sponsorshipMatériaux avancés pour capteurs optiques. - ANR-10-BLAN-0820
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enDiscussion on the Structure Stability and the Luminescence Switch under Irradiation of a Ce-Doped Elpasolite Compound.
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.201405784
dc.subject.halChimie/Matériaux
bordeaux.journalChemistry - A European Journal
bordeaux.page5242-5251
bordeaux.volume21
bordeaux.issue13
bordeaux.peerReviewedoui
hal.identifierhal-01135935
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01135935v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20-%20A%20European%20Journal&rft.date=2015&rft.volume=21&rft.issue=13&rft.spage=5242-5251&rft.epage=5242-5251&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=CORNU,%20Lucile&GAUDON,%20Manuel&VEBER,%20Philippe&VILLESUZANNE,%20Antoine&PECHEV,%20Stanislav&rft.genre=article


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