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Phosphate structure and lithium environments in lithium phosphorus oxynitride amorphous thin films
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Institut für Materialwissenschaft | |
| dc.contributor.author | CARRILLO SOLANO, Mercedes Alicia | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | DUSSAUZE, Marc | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | VINATIER, Philippe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CROGUENNEC, Laurence | |
| hal.structure.identifier | Theoretical and Physical Chemistry Institute | |
| dc.contributor.author | KAMITSOS, Efstratios I. | |
| hal.structure.identifier | Institut für Materialwissenschaft | |
| dc.contributor.author | HAUSBRAND, R. | |
| hal.structure.identifier | Institut für Materialwissenschaft | |
| dc.contributor.author | JAEGERMANN, Wolfram | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 0947-7047 | |
| dc.description.abstractEn | Lithium ion-conducting glasses attract wide interest for electrochemical applications like efficient energy storage devices. This work presents a structural study on involved bonding units, based on X-ray photoelectron spectroscopy and infrared spectroscopy, of lithium phosphorus oxide and oxynitride amorphous thin films prepared by RF magnetron sputtering. A thorough consideration of the mid- and far-infrared spectral regions demonstrated structural changes at the phosphate units and the lithium ion environments triggered by nitrogen incorporation and post-deposition thermal treatment. It was found that films prepared by sputtering in pure nitrogen atmosphere have about 75 % of their nitrogen atoms in sites doubly coordinated with phosphorus (P–N=P), and the rest in triply coordinated sites. It was shown also that nitrogen incorporation favors the stability of lithium ions, while annealing enhances ionic conductivity of the oxynitride films. | |
| dc.language.iso | en | |
| dc.publisher | Springer Verlag | |
| dc.subject.en | LiPON | |
| dc.subject.en | IR spectroscopy | |
| dc.subject.en | Thin film | |
| dc.subject.en | Lithium phosphorus oxynitride | |
| dc.subject.en | Glasses | |
| dc.title.en | Phosphate structure and lithium environments in lithium phosphorus oxynitride amorphous thin films | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1007/s11581-015-1573-1 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Ionics | |
| bordeaux.page | 471-481 | |
| bordeaux.volume | 22 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01294952 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01294952v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Ionics&rft.date=2016&rft.volume=22&rft.issue=4&rft.spage=471-481&rft.epage=471-481&rft.eissn=0947-7047&rft.issn=0947-7047&rft.au=CARRILLO%20SOLANO,%20Mercedes%20Alicia&DUSSAUZE,%20Marc&VINATIER,%20Philippe&CROGUENNEC,%20Laurence&KAMITSOS,%20Efstratios%20I.&rft.genre=article |
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