NDAYISHIMIYE, Arnaud; BUFFIERE, Sonia; DOURGES, Marie-Anne; LARGETEAU, Alain; PRAKASAM, Mythili; MORNET, Stéphane; KAMAN, Ondřej; ZDENĔK, Jirák; HEJTMÁNEK, Jiří; GOGLIO, Graziella

doi:10.1016/j.scriptamat.2018.01.013

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NDAYISHIMIYE, Arnaud
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

BUFFIERE, Sonia
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DOURGES, Marie-Anne
Institut des Sciences Moléculaires [ISM]

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Scripta Materialia. 2018, vol. 148, p. 15-19

Elsevier

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We report here the successful design of 0–3 type nanocomposites where 30 nm ferromagnetic metallically conducting cores of manganite La0.66Sr0.34MnO3 (LSMO) are discretely distributed in an insulating silica matrix. Starting from LSMO@SiO2 core@shell nanoparticles, hydrothermal sintering process was used as a low temperature densification route (300 °C, 350 MPa, 90 min) in presence of 0.2 M aqueous sodium hydroxide solution. This process based on a pressure solution creep in the contact zones between nanoparticles allows the design of complex microstructures preventing the grain growth of the cores and the formation of interphases between the cores and the matrix.< Leer menos

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Composites

Nanostructuration

Hydrothermal Sintering

Low-Temperature Water-Assisted Densification

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Design of 0–3 type nanocomposites using hydrothermal sintering

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