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Cyanide-bridged tetradecanuclear RuII3MII11 clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties

hal.structure.identifierDepartamento de Química Inorgánica
dc.contributor.authorHERRERA, Juan Manuel
hal.structure.identifierDepartamento de Química Inorgánica
dc.contributor.authorCOLACIO, Enrique
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierLaboratorio de Estudios Cristalográficos
dc.contributor.authorCHOQUESILLO-LAZARTE, Duane
hal.structure.identifierDepartment of Chemistry [Sheffield]
dc.contributor.authorWARD, Michael D.
dc.date.issued2008
dc.identifier.issn1359-7345
dc.description.abstractEnReaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(3-HAT)]6− with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enZinc
dc.subject.enCopper
dc.subject.enRuthenium
dc.subject.enLuminescence
dc.subject.enChromophore
dc.subject.enCyanometallate
dc.title.enCyanide-bridged tetradecanuclear RuII3MII11 clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties
dc.typeArticle de revue
dc.identifier.doi10.1039/b807364c
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Communications
bordeaux.page4460-4462
bordeaux.issue37
bordeaux.peerReviewedoui
hal.identifierhal-00326973
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00326973v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2008&rft.issue=37&rft.spage=4460-4462&rft.epage=4460-4462&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=HERRERA,%20Juan%20Manuel&COLACIO,%20Enrique&MATHONI%C3%88RE,%20Corine&CHOQUESILLO-LAZARTE,%20Duane&WARD,%20Michael%20D.&rft.genre=article


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