Design of stimuli-responsive surfaces prepared bysurface segregation of polypeptide-b-polystyrene diblock copolymers
PAPON, Eric
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Reduce
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Language
en
Article de revue
This item was published in
Macromolecules. 2008, vol. 41, n° 4, p. 1053-1056
American Chemical Society
English Abstract
The surface segregation has been found to be an appropriate method for preparing functionalized surfaces with polypeptide-b-polystyrene diblock copolymers. The preparation of stimuli-responsive surfaces containing polypeptide ...Read more >
The surface segregation has been found to be an appropriate method for preparing functionalized surfaces with polypeptide-b-polystyrene diblock copolymers. The preparation of stimuli-responsive surfaces containing polypeptide poly(L-glutamic acid) (PGA) segments at the surface by using amphiphilic polystyrene-b-poly(L-glutamic acid) block copolymers as surface modification agents has been demonstrated. Poly(L-glutamic acid), revealed at the surface by annealing in humid environment, has the capability of changing back and forth between a charged and a neutralized state giving a pH-responsive character to the surface. Such surfaces are currently being evaluated for different potential applications including cellular adhesion in which both surface charge density and structure are key parameters.Read less <
English Keywords
BLENDS
MEMBRANES
BRUSHES
DESIGN
POLYPEPTIDE
POLYMERS
POLYSTYRENE
BLOCK-COPOLYMERS
SURFACE SEGREGATION
RADICAL POLYMERIZATION
Origin
Hal imported