A new Organic–Inorganic hybrid compound (NH3(CH2)2C6H5)2[SnCl6]: Crystal structure, characterization, Hirshfeld surface analysis, DFT calculation, vibrational properties and biological evaluation
| hal.structure.identifier | Department of Physics | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | GEESI, Mohammed | |
| hal.structure.identifier | Department of Pharmaceutical Chemistry | |
| dc.contributor.author | RIADI, Yassine | |
| hal.structure.identifier | Department of Pharmaceutics | |
| hal.structure.identifier | Department of Medical Microbiology | |
| dc.contributor.author | IBNOUF, Elmutasim | |
| hal.structure.identifier | King Abdulaziz City for Science and Technology [Riyadh] [KACST] | |
| dc.contributor.author | ALJOHANI, Talal | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| dc.date.issued | 2021 | |
| dc.identifier.issn | 0022-4596 | |
| dc.description.abstractEn | In this study, the crystal structure of a new phase of organic–inorganic hybrid (NH3(CH2)2C6H5)2[SnCl6] was resolved at room temperature (monoclinic system), space group (P21/c), with unit cell parameters (a = 7.345(5) Å, b = 25.667(5) Å, c = 11.971(5) Å), β = 90.106(5)°, volume = 2256.8 (19) Å3 and Z = 4). The asymmetric unit cell consisted of a combination of [SnCl6]2– and two organic + NH3C2H4C6H5 cations. The crystal structure comprised alternating organic and inorganic layers stacked along the b-axis. The isolated octahedra formed a zero-dimensional anionic network. The crystal structure was stabilized by hydrogen bonding. Powder X-ray diffraction confirmed the phase purity. Hirshfeld surface and fingerprint plots elucidated the contribution of the H⋅⋅⋅Cl and H⋅⋅⋅H intermolecular interactions. DFT calculations confirmed the assignment of the Raman bands. Vibrational absorption bands were identified by micro-Raman spectroscopy. The antibacterial performance was investigated. Notably, this new compound was active against all of the tested bacteria. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | X-ray diffraction | |
| dc.subject.en | Hirshfeld surface | |
| dc.subject.en | DFT calculation | |
| dc.subject.en | Micro-Raman spectroscopy | |
| dc.subject.en | Antibacterial | |
| dc.title.en | A new Organic–Inorganic hybrid compound (NH3(CH2)2C6H5)2[SnCl6]: Crystal structure, characterization, Hirshfeld surface analysis, DFT calculation, vibrational properties and biological evaluation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jssc.2021.122587 | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Cristallographie | |
| bordeaux.journal | Journal of Solid State Chemistry | |
| bordeaux.page | 122587 | |
| bordeaux.volume | 304 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-03435026 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-03435026v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Solid%20State%20Chemistry&rft.date=2021&rft.volume=304&rft.spage=122587&rft.epage=122587&rft.eissn=0022-4596&rft.issn=0022-4596&rft.au=KAIBA,%20Abdellah&GEESI,%20Mohammed&RIADI,%20Yassine&IBNOUF,%20Elmutasim&ALJOHANI,%20Talal&rft.genre=article |
Files in this item
| Files | Size | Format | View |
|---|---|---|---|
|
There are no files associated with this item. |
|||