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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGAUDON, Manuel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAJIMEL, Jérôme
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorHEINTZ, Jean-Marc
hal.structure.identifierInstitut für Chemie
dc.contributor.authorFEIST, Michael
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDAMBOURNET, Damien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTRESSAUD, Alain
dc.date.issued2008
dc.identifier.issn0022-1139
dc.description.abstractEnFluorinated transition aluminas (Al2−x/3O3−xFx) with hexagonal platelet shape were synthesized via decomposition of α-AlF3 under air; they are thermally stable up to 1000 °C and exhibit at 1150 °C a weight loss with volume reduction caused by fluorine departure corresponding to a phase transition toward corundum alumina. The different characterizations performed in this study are structural (XRD), chemical (TGA-MS and microprobe analysis) and morphological (SEM, TEM and dilatometry). The evidence provided from this study is consistent with the formation of an Al–O–F phase as an intermediate compound in the pyrohydrolysis of an aluminium trifluoride phase to α-Al2O3.
dc.language.isoen
dc.publisherElsevier
dc.title.enFluorinated transition alumina with Al2−x/3O3−xFx compositions: Thermal, chemical, structural and morphological investigations
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jfluchem.2008.09.004
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Fluorine Chemistry
bordeaux.page1173-1179
bordeaux.volume129
bordeaux.issue12
bordeaux.peerReviewedoui
hal.identifierhal-00346775
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00346775v1
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