High-pressure Raman investigation of the Pb-free relaxor BaTi0.65Zr0.35O3
BOUVIER, P.
Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces [LEPMI ]
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Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces [LEPMI ]
BOUVIER, P.
Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces [LEPMI ]
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Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces [LEPMI ]
Language
en
Article de revue
This item was published in
Physical Review B: Condensed Matter and Materials Physics (1998-2015). 2004, vol. 69 (9), p. 092104 (4 p.)
American Physical Society
English Abstract
We report high-pressure Raman measurements (up to 27 GPa) on the perovskite-type relaxor ferroelectric BaTi0.65Zr0.35O3(BTZ35). Distinct changes of the Raman spectra with increasing pressure illustrate that BTZ35 presents ...Read more >
We report high-pressure Raman measurements (up to 27 GPa) on the perovskite-type relaxor ferroelectric BaTi0.65Zr0.35O3(BTZ35). Distinct changes of the Raman spectra with increasing pressure illustrate that BTZ35 presents important pressure instabilities leading to at least two phase transitions around 5.7 GPa and 15.1 GPa, respectively. The observed pressure-induced spectral changes for BTZ35 are reminiscent of features that have been observed for pure BaTiO3, thus for a classic ferroelectric. The latter is surprising since earlier reports indicate a relaxor-characteristic Raman signature as a function of temperature, thus illustrating that BTZ35 might well occupy a peculiar niche in perovskite-type ferroelectrics.Read less <
English Keywords
Raman spectroscopy
Relaxor ferroelectric
BTZ35
High pressure
Origin
Hal imported