Show simple item record

Tuning the activity and selectivity of polymerised ionic liquid-stabilised ruthenium nanoparticles through anion exchange reactions

hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorPARIDA, Dambarudhar
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorBAKKALI-HASSANI, Camille
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLEBRAUD, Éric
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
dc.contributor.authorSCHATZ, Christophe
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 2 LCPO : Biopolymers & Bio-sourced Polymers
dc.contributor.authorGRELIER, Stéphane
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorTATON, Daniel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 1 LCPO : Polymerization Catalyses & Engineering
dc.contributor.authorVIGNOLLE, Joan
dc.date.issued2022
dc.identifier.issn2040-3364
dc.description.abstractEnThe development of highly active and selective heterogeneous-based catalysts with tailorable properties is not only a fundamental challenge, but is also crucial in the context of energy savings and sustainable chemistry. Here, we show that ruthenium nanoparticles (RuNPs) stabilised with simple polymerised ionic liquids (PILs) based on N-vinyl imidazolium led to highly active and robust nano-catalysts in hydrogenation reactions, both in water and organic media. Of particular interest, their activity and selectivity could simply be tuned through counter-anions exchange reactions. Hence, as a proof of concept, the activity of RuNPs could be reversibly turned on and off in the hydrogenation of toluene, while in the case of styrene, the hydrogenation could be selectively switched from ethylbenzene to ethylcyclohexane upon anion metathesis. According to X-Ray photo-electron spectroscopy (XPS) and Dynamic light scattering (DLS) analysis, these effects could originate from the relative hydrophobicity and solvation of the PIL corona but also from the nature and strength of the PIL-Ru interactions.
dc.description.sponsorshipTransformation catalytique de la lignine en bio-carburants par des nanoparticules métalliques stabilisées par des poly(liquides ioniques) à tâches spécifiques - ANR-14-CE05-0027
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/
dc.title.enTuning the activity and selectivity of polymerised ionic liquid-stabilised ruthenium nanoparticles through anion exchange reactions
dc.typeArticle de revue
dc.identifier.doi10.1039/d1nr07628k
dc.subject.halChimie/Catalyse
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Polymères
bordeaux.journalNanoscale
bordeaux.page4635-4643
bordeaux.volume14
bordeaux.issue12
bordeaux.peerReviewedoui
hal.identifierhal-03601213
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03601213v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Nanoscale&rft.date=2022&rft.volume=14&rft.issue=12&rft.spage=4635-4643&rft.epage=4635-4643&rft.eissn=2040-3364&rft.issn=2040-3364&rft.au=PARIDA,%20Dambarudhar&BAKKALI-HASSANI,%20Camille&LEBRAUD,%20%C3%89ric&SCHATZ,%20Christophe&GRELIER,%20St%C3%A9phane&rft.genre=article


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record