A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study
| hal.structure.identifier | Department of Physics | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | GEESI, Mohammed | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| dc.date.issued | 2022-05 | |
| dc.identifier.issn | 0277-5387 | |
| dc.description.abstractEn | Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystallizes in a monoclinic system with C2/c space group and unit cell parameters (a = 32.071(5) Å, b = 5.827(5) Å, c = 11.596(5) Å, β = 94.858(5) °, and Z = 4) at room temperature. The crystal structure exploration reveal the stabilization of the crystal packing is carried out by a complex network of hydrogen interactions that lead formation of layered organic- inorganic hybrid stacked along the a-axis. The intermolecular interactions were elucidated by Hirchfeld surface analysis and fingerprint plots. The vibration modes were probed by Micro-Raman spectroscopy. Also, the vibrating sample magnetometer (VSM) measurement shows the ferromagnetism aspect of the compound as well as the energy gap was estimated from UV–visible absorption spectroscopy. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Organic- inorganic hybrid | |
| dc.subject.en | XRD | |
| dc.subject.en | Raman spectroscopy | |
| dc.subject.en | VSM | |
| dc.subject.en | Hirshfeld surface | |
| dc.subject.en | DFT | |
| dc.title.en | A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.poly.2022.115717 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Polyhedron | |
| bordeaux.page | 115717 | |
| bordeaux.volume | 217 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-03602136 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-03602136v1 | |
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