The crystal structure of eulytite Pb<sub>3</sub>BiV<sub>3</sub>O<sub>12</sub>
| hal.structure.identifier | Solid State and Structural Chemistry Unit | |
| dc.contributor.author | SAHOO, Prangya Parimita | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GAUDIN, Etienne | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DARRIET, Jacques | |
| hal.structure.identifier | Solid State and Structural Chemistry Unit | |
| dc.contributor.author | GURU ROW, T. N. | |
| dc.date.issued | 2009 | |
| dc.identifier.issn | 0025-5408 | |
| dc.description.abstractEn | The crystal structure of Pb<sub>3</sub>BiV<sub>3</sub>O<sub>12</sub> was solved using single-crystal X-ray diffraction technique. The compound crystallizes in the cubic system I43d (No. 220) with eulytite structure with <i>a</i> = 10.7490(7) Å, <i>V</i> = 1241.95(14) Å<sup>3</sup> and <i>Z</i> = 4. The final <i>R</i><sub>1</sub> value of 0.0198 (<i>w</i><i>R</i><sub>2</sub>=0.0384) was achieved for 359 independent reflections during the structure refinement. The Pb<sup>2+</sup> and Bi<sup>3+</sup> cations occupy the special position (<i>16c</i>) while the oxygen anions occupy the general position (<i>48e</i>) in the crystal structure. Unlike many other eulytite compounds, all the crystallographic positions are fully occupied. The structure consists of edge-shared Pb/Bi octahedra linked at the corners to independent [VO<sub>4</sub>]<sup>3−</sup> tetrahedra units, generating a eulytite-type network in the crystal lattice. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Inorganic compound | |
| dc.subject.en | Oxides | |
| dc.subject.en | Crystal growth | |
| dc.subject.en | X-ray diffraction | |
| dc.subject.en | Crystal structure | |
| dc.title.en | The crystal structure of eulytite Pb<sub>3</sub>BiV<sub>3</sub>O<sub>12</sub> | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.materresbull.2008.09.022 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Materials Research Bulletin | |
| bordeaux.page | 812-816 | |
| bordeaux.volume | 44 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00363410 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00363410v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Research%20Bulletin&rft.date=2009&rft.volume=44&rft.issue=4&rft.spage=812-816&rft.epage=812-816&rft.eissn=0025-5408&rft.issn=0025-5408&rft.au=SAHOO,%20Prangya%20Parimita&GAUDIN,%20Etienne&DARRIET,%20Jacques&GURU%20ROW,%20T.%20N.&rft.genre=article |
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