Show simple item record

Novel optical amorphous phosphate materials with a low melting temperature

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
dc.contributor.authorKASER, Simon
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
dc.contributor.authorGUÉRINEAU, Théo
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSTRUTYNSKI, Clément
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorZAKI, Reda
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDUSSAUZE, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDURAND, Etienne
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
dc.contributor.authorMESSADDEQ, Sandra
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDANTO, Sylvain
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
dc.contributor.authorMESSADDEQ, Younès
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARDINAL, Thierry
dc.date.issued2022
dc.description.abstractEnWe report on the synthesis of transparent amorphous hydrated phosphate materials at low temperatures (as low as 300 °C) in the [50P2O5 - (25 -x/2)K2O - (25 - x/2)Na2O - xZnO] - nH2O (0–25 mol%). These new transparent materials were studied by Raman and FTIR spectroscopies. The structure of the hydrated phosphates is proposed to consist of both short phosphate chains and isolated phosphate groups linked together by hydrogen bonds. Containing up to 40 mol% of water, most of the physicochemical properties remain unchanged, except for the characteristic glass temperatures. Moreover, the most hydrated amorphous phosphate materials tend to exhibit a softening phenomenon below 150 °C. The addition of ZnO to these phosphate materials offers better glass stability against moisture while maintaining the glass properties of zinc-free materials. Hence, these new amorphous transparent materials pave the way for novel low melting temperature optical materials.
dc.description.sponsorshipImPRession laser de fibres exOtiques Multi-MaTEriaux
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enNovel optical amorphous phosphate materials with a low melting temperature
dc.typeArticle de revue
dc.identifier.doi10.1039/D1MA00995H
dc.subject.halChimie/Matériaux
dc.description.sponsorshipEuropeCentre for functional and surface-functionalized glasses
bordeaux.journalMaterials Advances
bordeaux.page4600-4607
bordeaux.issue11
bordeaux.peerReviewedoui
hal.identifierhal-03667642
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03667642v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Advances&rft.date=2022&rft.issue=11&rft.spage=4600-4607&rft.epage=4600-4607&rft.au=KASER,%20Simon&GU%C3%89RINEAU,%20Th%C3%A9o&STRUTYNSKI,%20Cl%C3%A9ment&ZAKI,%20Reda&DUSSAUZE,%20Marc&rft.genre=article


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record