A new family of diamagnetic macrocyclic Fe(II) compounds exhibiting the LIESST effect at high temperatures.
WANG, Hongfeng
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Huazhong University of Science and Technology [Wuhan] [HUST]
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Huazhong University of Science and Technology [Wuhan] [HUST]
WANG, Hongfeng
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Huazhong University of Science and Technology [Wuhan] [HUST]
< Leer menos
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Huazhong University of Science and Technology [Wuhan] [HUST]
Idioma
en
Article de revue
Este ítem está publicado en
Dalton Transactions. 2014, vol. 43, n° 41, p. 15346-15350
Royal Society of Chemistry
Resumen en inglés
The photomagnetic properties of a new Fe(ii) macrocyclic family [Fe(LxyzN5)(CN)2]·nH2O were investigated with respect to the T(LIESST) versus T1/2 relationship. These compounds are diamagnetic below 400 K with T(LIESST) ...Leer más >
The photomagnetic properties of a new Fe(ii) macrocyclic family [Fe(LxyzN5)(CN)2]·nH2O were investigated with respect to the T(LIESST) versus T1/2 relationship. These compounds are diamagnetic below 400 K with T(LIESST) values above 100 K, which indicates that this family presents an unconventional LIESST effect that is much higher than the expected T0 = 180 K line for macrocyclic complexes.< Leer menos
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