TRESSAUD, Alain; DURAND, Etienne; LABRUGÈRE, Christine; KHARITONOV, Alexander P.; SIMBIRTSEVA, Galina V.; KHARITONOVA, Larisa N.; DUBOIS, Marc

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TRESSAUD, Alain
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DURAND, Etienne
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

LABRUGÈRE, Christine
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Article de revue

Ce document a été publié dans

Acta Chimica Slovenica. 2013, vol. 60, n° 3, p. 495-504

Slovenian Chemical Society

Résumé en anglais

Fluorination processes of polymer surfaces are able to lead to drastic modifications of the surface properties without changing the bulk characteristics of the virgin material. In this paper, two types of polymers, i.e. ultrahigh molecular weight polyethylene (UHMWPE) and high density polyethylene (HDPE), are considered. The surface of these materials have been modified using two different fluorination routes, both carried out at room temperature: the direct fluorination with 10% F2 + 90% He gaseous mixtures and the radio-frequency plasma-enhanced fluorination (PEF) using either O2/CF4 mixtures or c-C4F8. The effect of these processes on the surface of the polymer samples are compared using mostly XPS results. The different components of the C1s spectra are assigned in term of CFx bonding, giving valuable information on the surface fluorination rate.< Réduire

Mots clés en anglais

F2-gas fluorination

Fluorinated rf-plasmas

UHMWPE

HDPE

Surface modification

XPS

Coatings

Origine

Importé de hal

Unités de recherche

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026