Benzyltriphenylphosphonium dichloridotriphenylstannate(IV)
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en
Article de revue
Ce document a été publié dans
Acta Crystallographica Section E : Structure Reports Online [2001-2014]. 2013, vol. 69, n° 1, p. m42
International Union of Crystallography
Résumé en anglais
The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3]+ cations and [SnPh3Cl2]- anions in which the SnIV atom is linked to two Cl atoms and three phenyl groups ...Lire la suite >
The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3]+ cations and [SnPh3Cl2]- anions in which the SnIV atom is linked to two Cl atoms and three phenyl groups in a trigonal-bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetrahedral geometry. In the crystal, the cations and the anions are connected by C-H...Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.< Réduire
Mots clés en anglais
Crystal structure
Benzyltriphenylphosphonium dichloridotriphenylstannate(IV)
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