DELEUZE, Charles; DELVILLE, Marie-Hélène; PELLERIN, V.; DERAIL, Christophe; BILLON, Laurent

doi:10.1021/ma900709x

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

DELEUZE, Charles
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]

DELVILLE, Marie-Hélène
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

PELLERIN, V.
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]

Idioma

Article de revue

Este ítem está publicado en

International Journal of Biological Macromolecules. 2009, vol. 42, n° 14, p. 5303-5309

Elsevier

Resumen en inglés

Hybrid materials have been developed through the synthesis of colloidal silica surrounded by elastomer polymer brushes. These core@shell materials have been achieved by the use of "nitroxide-mediated polymerization" (NMP) associated with a "grafting from" method. The living and controlled characteristics of the polymerization allow TEM observations of well-monodisperse core@shell nanohybrids. We present herein the synthetic process to create homogeneous smoothness particles surface associated with a strong adhesive property. The brush thickness is tuned in order to compare with molecular dynamic equations through the tailoring of the grafting density and the molecular weight. Finally, these particles were used as elementary adhesive building blocks and self-assembled by a dip-coating process to form a monolayered material. Its diffraction under light is described on a large-scale material as well as the elastomeric polymer brushes layer influence.< Leer menos

Metadatos

Licencia de uso del documento

Hybrid core@soft shell particles as adhesive elementary building blocks for collaidal crystals

Idioma

Este ítem está publicado en

Resumen en inglés

DOI

Orígen

Centros de investigación