Hybrid core@soft shell particles as adhesive elementary building blocks for collaidal crystals
DELEUZE, Charles
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
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Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
DELEUZE, Charles
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
DERAIL, Christophe
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
BILLON, Laurent
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
< Reduce
Institut pluridisciplinaire de recherche sur l'environnement et les matériaux [IPREM]
Language
en
Article de revue
This item was published in
International Journal of Biological Macromolecules. 2009, vol. 42, n° 14, p. 5303-5309
Elsevier
English Abstract
Hybrid materials have been developed through the synthesis of colloidal silica surrounded by elastomer polymer brushes. These core@shell materials have been achieved by the use of "nitroxide-mediated polymerization" (NMP) ...Read more >
Hybrid materials have been developed through the synthesis of colloidal silica surrounded by elastomer polymer brushes. These core@shell materials have been achieved by the use of "nitroxide-mediated polymerization" (NMP) associated with a "grafting from" method. The living and controlled characteristics of the polymerization allow TEM observations of well-monodisperse core@shell nanohybrids. We present herein the synthetic process to create homogeneous smoothness particles surface associated with a strong adhesive property. The brush thickness is tuned in order to compare with molecular dynamic equations through the tailoring of the grafting density and the molecular weight. Finally, these particles were used as elementary adhesive building blocks and self-assembled by a dip-coating process to form a monolayered material. Its diffraction under light is described on a large-scale material as well as the elastomeric polymer brushes layer influence.Read less <
Origin
Hal imported