Structure topology in silver(I)-(poly)chalcogenide halides : a helpful tool to understand structure relations and properties
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | NILGES, Tom | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | BAWOHL, Melanie | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | MESSEL, Julia | |
| hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
| dc.contributor.author | OSTERS, Oliver | |
| dc.date.issued | 2010 | |
| dc.identifier.issn | 0044-2313 | |
| dc.description.abstractEn | Recent progress in the field of silver(I)-chalcogenide halides and silver(I)-polychalcogenide halides led to the discovery of a reasonable number of new phases, solid solutions and even a new substance class of materials with favorable electronic and thermoelectric properties. Most of these new compounds are characterized by a pronounced ion mobility, polymorphism, and complex structures, which result in severe problems during the structure solution, the refinement, and even the description of the crystal structures. Herein we report on a very simple but effective building principle and a topological structure approach, which are both based on the separate description of anion substructures and the introduction of discrete building blocks. Such a topological principle helps to understand the complex structural relations and allows one to discuss all known chalcogenide and polychalcogenide halides in a continuous sequence of compounds. Following this principle it is possible to understand physical properties and to predict new phases in the system. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Silver | |
| dc.subject.en | Chalcogens | |
| dc.subject.en | Chalcogenide halides | |
| dc.subject.en | Polychalcogenide halides | |
| dc.subject.en | Structure topology | |
| dc.subject.en | Ion mobility | |
| dc.title.en | Structure topology in silver(I)-(poly)chalcogenide halides : a helpful tool to understand structure relations and properties | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/zaac.200900425 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie | |
| bordeaux.page | 15-18 | |
| bordeaux.volume | 636 | |
| bordeaux.issue | 1 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00459889 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00459889v1 | |
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