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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTRESSAUD, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLABRUGÈRE, Christine
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDURAND, Etienne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSERIER, Hélène
hal.structure.identifierInstitute of Geology and Nature Management
dc.contributor.authorDEMYANOVA, Larisa P.
dc.date.issued2010
dc.identifier.issn0734-2101
dc.description.abstractEnThe<sup> </sup>effect of fluorination on various types of phyllosilicate minerals has<sup> </sup>been investigated. Two different fluorination techniques have been used: direct<sup> </sup>F<sub>2</sub> gas and cold radio frequency plasma involving <i>c</i>-C<sub>4</sub>F<sub>8</sub> or<sup> </sup>O<sub>2</sub>/CF<sub>4</sub> mixtures. The modifications of the surface composition and properties<sup> </sup>have been followed mostly by x-ray photoelectron spectroscopy (XPS). Depending<sup> </sup>of the fluorination reagents, a reactive etching process involving <i>M</i>-F<sup> </sup>bonding occurs (direct F<sub>2</sub> gas; O<sub>2</sub>–CF<sub>4</sub> rf plasma) or a<sup> </sup>carbon fluoride deposition takes place (<i>c</i>-C<sub>4</sub>F<sub>8</sub> rf plasma). In the<sup> </sup>case of F<sub>2</sub>-gas treated minerals, Si 2<i>p</i> XPS signal accounts<sup> </sup>for the presence of fluorinated Si environments.
dc.language.isoen
dc.publisherAmerican Vacuum Society
dc.title.enSurface modification of phyllosilicate minerals by fluorination methods
dc.typeArticle de revue
dc.identifier.doi10.1116/1.3328826
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Vacuum Science & Technology A
bordeaux.page373-381
bordeaux.volume28
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00470646
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00470646v1
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