Preparation of Remarkably Tough PolyHIPE Materials via Polymerization of Oil-in-Water HIPEs Involving 1-Vinyl-5-Aminotetrazole
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
hal.structure.identifier | Université Sciences et Technologies - Bordeaux 1 [UB] | |
dc.contributor.author | YOUSSEF, Carlos | |
hal.structure.identifier | Université Sciences et Technologies - Bordeaux 1 [UB] | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | BACKOV, Rénal | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | TRÉGUER-DELAPIERRE, Mona | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
hal.structure.identifier | Université Sciences et Technologies - Bordeaux 1 [UB] | |
dc.contributor.author | BIROT, Marc | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
hal.structure.identifier | Université Sciences et Technologies - Bordeaux 1 [UB] | |
dc.contributor.author | DELEUZE, Hervé | |
dc.date.issued | 2010 | |
dc.identifier.issn | 0887-624X | |
dc.description.abstractEn | Interconnected microcellular polymeric monoliths having unexpected high mechanical strength have been prepared using the high internal phase emulsion (HIPE) methodology. Oil-in water concentrated emulsions of aqueous 1-vinyl-5-amino [1,2,3,4]tetrazole (1-VAT) mixed with a low molar ratio (7%) ofN,N0-methylenebisacrylamide as crosslinking agent were prepared using dodecane as dispersed phase and a mixture of hydrophilic surfactants. ''Reverse'' polyHIPE materials were obtained after radical copolymerization, solvent extraction, and drying. Their morphology, chemical composition, and physicochemical behavior are discussed. | |
dc.language.iso | en | |
dc.publisher | Wiley | |
dc.subject.en | atom transfer radical polymerization (ATRP) | |
dc.subject.en | block copolymers | |
dc.subject.en | nitroxide radical coupling | |
dc.subject.en | polystyrene | |
dc.subject.en | single electron transfer living radical coupling | |
dc.title.en | Preparation of Remarkably Tough PolyHIPE Materials via Polymerization of Oil-in-Water HIPEs Involving 1-Vinyl-5-Aminotetrazole | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/pola.24075 | |
dc.subject.hal | Chimie/Polymères | |
bordeaux.journal | Journal of Polymer Science Part A: Polymer Chemistry | |
bordeaux.page | pp. 2942-2947 | |
bordeaux.volume | 48 | |
bordeaux.issue | 13 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00486272 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00486272v1 | |
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