Reversible Thermally and Photoinduced Electron Transfer in a Cyano-Bridged {Fe2Co2} Square Complex
hal.structure.identifier | Department of Chemistry & Biochemistry, Missouri | |
dc.contributor.author | ZHANG, Yuanzhu | |
hal.structure.identifier | Key Laboratory of Pesticide and Chemical Biology of Ministry of Education | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | LI, Dongfeng | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | CLÉRAC, Rodolphe | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | KALISZ, Marguerite | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MATHONIÈRE, Corine | |
hal.structure.identifier | Department of Chemistry & Biochemistry, Missouri | |
dc.contributor.author | HOLMES, Stephen M. | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1433-7851 | |
dc.description.abstractEn | Flip to be square: Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe2Co2} complex undergoes reversible thermally and light-induced changes in optical and magnetic properties. This instability is induced by an intramolecular electron transfer, as oberved in three-dimensional Co/Fe Prussian blue compounds (see picture). | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.subject.en | bistability | |
dc.subject.en | cyanometatlates | |
dc.subject.en | electron transfer | |
dc.subject.en | magnetic properties | |
dc.subject.en | photochromism | |
dc.subject.en | thermochromism | |
dc.title.en | Reversible Thermally and Photoinduced Electron Transfer in a Cyano-Bridged {Fe2Co2} Square Complex | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/anie.201000765 | |
dc.subject.hal | Chimie/Matériaux | |
dc.subject.hal | Chimie/Chimie de coordination | |
bordeaux.journal | Angewandte Chemie International Edition | |
bordeaux.page | pp. 3752-3756 | |
bordeaux.volume | 49 | |
bordeaux.issue | 22 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00486636 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00486636v1 | |
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