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Growth of {Tb<sub>3</sub>}[Sc<sub>2−<i>x</i></sub>Lu<sub><i>x</i></sub>](Al<sub>3</sub>)O<sub>12</sub> Single Crystals for Visible-Infrared Optical Isolators

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorSHIMAMURA, Kiyoshi
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorKITO, Takayuki
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorCASTEL, Elias
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorLATYNINA, Anastasiya
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorMOLINA, Pablo
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierNational Institute for Materials Science [NIMS]
dc.contributor.authorVILLORA, Encarnacion G.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPRAKASAM, Mythili
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVEBER, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHAMINADE, Jean-Pierre
hal.structure.identifierNational Institute for Materials Science [NIMS]
hal.structure.identifierFujikura Ltd.
dc.contributor.authorFUNAKI, Akiharu
hal.structure.identifierNational Institute for Materials Science [NIMS]
hal.structure.identifierFujikura Ltd.
dc.contributor.authorHATANAKA, Tsubasa
hal.structure.identifierFujikura Ltd.
dc.contributor.authorNAOE, Kunihiro
dc.date.issued2010
dc.identifier.issn1528-7483
dc.description.abstractEn{Tb3}[Sc2−xLux](Al3)O12 crystals have been grown and investigated for the first time for magneto-optical applications. Tb3Al5O12 exhibits the best magneto-optical features; however, its incongruent melting nature has led to the industrial use of Tb3Ga5O12. Tb3Sc2Al3O12 had been proposed as an alternative to Tb3Al5O12, but unfortunately its growth also presents several drawbacks. The present investigation shows that by the isovalent substitution of Sc3+ by Lu3+ in the octahedral site of the garnet structure, it is possible to improve the growth characteristics while preserving the superior magneto-optical properties. We demonstrate that {Tb3}[Sc2−xLux](Al3)O12 crystals show a higher visible transparency and a larger Faraday rotation than Tb3Ga5O12 crystals. {Tb3}[Sc2−xLux](Al3)O12 is therefore a very promising material in particular for new magneto-optical applications in the visible-near IR wavelength region.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enGrowth of {Tb<sub>3</sub>}[Sc<sub>2−<i>x</i></sub>Lu<sub><i>x</i></sub>](Al<sub>3</sub>)O<sub>12</sub> Single Crystals for Visible-Infrared Optical Isolators
dc.typeArticle de revue
dc.identifier.doi10.1021/cg100277w
dc.subject.halChimie/Matériaux
bordeaux.journalCrystal Growth & Design
bordeaux.page3466-3470
bordeaux.volume10
bordeaux.issue8
bordeaux.peerReviewedoui
hal.identifierhal-00522808
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00522808v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Crystal%20Growth%20&%20Design&amp;rft.date=2010&amp;rft.volume=10&amp;rft.issue=8&amp;rft.spage=3466-3470&amp;rft.epage=3466-3470&amp;rft.eissn=1528-7483&amp;rft.issn=1528-7483&amp;rft.au=SHIMAMURA,%20Kiyoshi&amp;KITO,%20Takayuki&amp;CASTEL,%20Elias&amp;LATYNINA,%20Anastasiya&amp;MOLINA,%20Pablo&amp;rft.genre=article


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