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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAYER, Charlotte
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHEVALIER, Bernard
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGORSSE, Stéphane
dc.date.issued2010
dc.identifier.issn0925-8388
dc.description.abstractEnMagnetocaloric effect and refrigeration capacity (RC) of Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> and Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> melt-spun nanocomposites are investigated. It is found that the nanocrystallites formed in the amorphous matrix are different between melt-spun Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> and Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> samples. Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> ribbons exhibit multiple second-order transitions in accordance to their composite nature whereas Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> ribbons display only one magnetic transition. The occurrence of several transitions increases the gap of temperature at half maximum value of the Δ<i>S</i><sub><i>M</i></sub> magnetic entropy, thus increasing the RC values of these materials. The use of Mn as transition metal induces Curie temperature values around 170–180 K and an antiferromagnetic coupling with Gd reducing the overall magnetization compared to that calculated considering the free Gd<sup>3+</sup> ion.
dc.language.isoen
dc.publisherElsevier
dc.subject.enMetallic glasses
dc.subject.enNanocomposites
dc.subject.enX-ray powder diffraction
dc.subject.enMagnetocaloric effect
dc.title.enMagnetic and magnetocaloric properties of the ternary Gd-based metallic glasses Gd<sub>60</sub>Mn<sub>30</sub>X<sub>10</sub>, with X = Al, Ga, In
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jallcom.2010.07.210
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Alloys and Compounds
bordeaux.page370-375
bordeaux.volume507
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00530391
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00530391v1
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