Magnetic and magnetocaloric properties of the ternary Gd-based metallic glasses Gd<sub>60</sub>Mn<sub>30</sub>X<sub>10</sub>, with X = Al, Ga, In
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MAYER, Charlotte | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHEVALIER, Bernard | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GORSSE, Stéphane | |
dc.date.issued | 2010 | |
dc.identifier.issn | 0925-8388 | |
dc.description.abstractEn | Magnetocaloric effect and refrigeration capacity (RC) of Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> and Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> melt-spun nanocomposites are investigated. It is found that the nanocrystallites formed in the amorphous matrix are different between melt-spun Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> and Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> samples. Gd<sub>60</sub>Mn<sub>30</sub>Ga<sub>10</sub> ribbons exhibit multiple second-order transitions in accordance to their composite nature whereas Gd<sub>60</sub>Mn<sub>30</sub>In<sub>10</sub> ribbons display only one magnetic transition. The occurrence of several transitions increases the gap of temperature at half maximum value of the Δ<i>S</i><sub><i>M</i></sub> magnetic entropy, thus increasing the RC values of these materials. The use of Mn as transition metal induces Curie temperature values around 170–180 K and an antiferromagnetic coupling with Gd reducing the overall magnetization compared to that calculated considering the free Gd<sup>3+</sup> ion. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Metallic glasses | |
dc.subject.en | Nanocomposites | |
dc.subject.en | X-ray powder diffraction | |
dc.subject.en | Magnetocaloric effect | |
dc.title.en | Magnetic and magnetocaloric properties of the ternary Gd-based metallic glasses Gd<sub>60</sub>Mn<sub>30</sub>X<sub>10</sub>, with X = Al, Ga, In | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.jallcom.2010.07.210 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Alloys and Compounds | |
bordeaux.page | 370-375 | |
bordeaux.volume | 507 | |
bordeaux.issue | 2 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00530391 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00530391v1 | |
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