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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBERTHELOT, Romain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPOLLET, Michaël
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDOUMERC, Jean-Pierre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELMAS, Claude
dc.date.issued2011
dc.identifier.issn0020-1669
dc.description.abstractEnA new polytype of AgCoO(2) delafossite has been prepared from the ordered OP4-(Li/Na)CoO(2) layered compound using ion-exchange reaction in molten salts. As expected from the structural model assuming a topotactic process, the lamellar structure of this new polytype is an alternate combination of the already known 2H and 3R delafossite polytypes. It crystallizes in the P6(3)/mmc space group with cell parameters a(hex.) = 2.871(1) Å and c(hex.) = 24.448(1) Å. Thermal stability, morphology characterization, and electrical properties are reported here and compared with those of the 2H and 3R AgCoO(2) polytypes.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enFirst Experimental Evidence of a New D4-AgCoO(2) Delafossite Stacking.
dc.typeArticle de revue
dc.identifier.doi10.1021/ic2002354
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page4529-4536
bordeaux.volume50
bordeaux.issue10
bordeaux.peerReviewedoui
hal.identifierhal-00593856
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00593856v1
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