First Experimental Evidence of a New D4-AgCoO(2) Delafossite Stacking.
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | BERTHELOT, Romain | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | POLLET, Michaël | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DOUMERC, Jean-Pierre | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DELMAS, Claude | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0020-1669 | |
dc.description.abstractEn | A new polytype of AgCoO(2) delafossite has been prepared from the ordered OP4-(Li/Na)CoO(2) layered compound using ion-exchange reaction in molten salts. As expected from the structural model assuming a topotactic process, the lamellar structure of this new polytype is an alternate combination of the already known 2H and 3R delafossite polytypes. It crystallizes in the P6(3)/mmc space group with cell parameters a(hex.) = 2.871(1) Å and c(hex.) = 24.448(1) Å. Thermal stability, morphology characterization, and electrical properties are reported here and compared with those of the 2H and 3R AgCoO(2) polytypes. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.title.en | First Experimental Evidence of a New D4-AgCoO(2) Delafossite Stacking. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/ic2002354 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Inorganic Chemistry | |
bordeaux.page | 4529-4536 | |
bordeaux.volume | 50 | |
bordeaux.issue | 10 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00593856 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00593856v1 | |
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