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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLATASTE, Emilie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDEMOURGUES, Alain
hal.structure.identifierMarion Technologies
dc.contributor.authorSALMI, J.
hal.structure.identifierMarion Technologies
dc.contributor.authorNAPOREA, C.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGAUDON, Manuel
dc.date.issued2011
dc.identifier.issn0143-7208
dc.description.abstractEnIrreversible thermochromism over a wide temperature range has been observed from the decomposition of a mixture of a barium carbonate and a metal oxide. The control of the reaction temperature can be predicted from the calculation of the Madelung energy of the barium/transition metal mixed oxide formed consecutively with the decarbonatation. Moreover, the Madelung energy of this formed mixed oxide may be predicted from bond valence considerations. This study offers a simple predictive approach to propose temperature indicators with significant optical contrast and a thermochromic temperature varying between 400 and 1200 °C.
dc.language.isoen
dc.publisherElsevier
dc.subject.enInorganic pigments
dc.subject.enThermochromism
dc.subject.enMetal oxides
dc.subject.enBarium carbonates
dc.subject.enColour
dc.subject.enBond Valence
dc.title.enThermochromic behavior (400 < T °C < 1200 °C) of barium carbonate/binary metal oxide mixtures
dc.typeArticle de revue
dc.identifier.doi10.1016/j.dyepig.2011.05.016
dc.subject.halChimie/Matériaux
bordeaux.journalDyes and Pigments
bordeaux.page396-403
bordeaux.volume91
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-00606906
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00606906v1
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