(Li/Ag)CoO(2): A New Intergrowth Cobalt Oxide Composed of Rock Salt and Delafossite Layers.
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | BERTHELOT, Romain | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | POLLET, Michaël | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DOUMERC, Jean-Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DELMAS, Claude | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | A new ordered (Li/Ag)CoO(2) layered compound with an unusual oxygen packing combining rock salt and delafossite layers is obtained during the (Li(+), Na(+))/Ag(+) ionic exchange from the OP4-(Li/Na)CoO(2) precursor. This compound is actually an intermediate step to the final D4-AgCoO(2) delafossite and can be isolated thanks to the kinetics difference between the Li(+)/Ag(+) and Na(+)/Ag(+) exchange processes. It crystallizes in the P6(3)/mmc space group with cell parameters a(hex.) = 2.848(3) Å and c(hex.) = 21.607(7) Å. The details of the structure as well as its thermal stability and transport properties are presented and discussed. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.title.en | (Li/Ag)CoO(2): A New Intergrowth Cobalt Oxide Composed of Rock Salt and Delafossite Layers. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ic200534x | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 6649-6655 | |
| bordeaux.volume | 50 | |
| bordeaux.issue | 14 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00607966 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00607966v1 | |
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