Tunable magnetocaloric effect in Gd-based glassy ribbons
Language
en
Article de revue
This item was published in
Journal of Applied Physics. 2011, vol. 110, n° 5, p. 053920 (7 p.)
American Institute of Physics
English Abstract
The series of glassy ribbons Gd60M30In10 (M = Mn, Co, Ni, Cu) was synthesized by melt-spinning. The change of transition element M in these Gd-based metallic glasses was proven to induce huge variations of the Curie ...Read more >
The series of glassy ribbons Gd60M30In10 (M = Mn, Co, Ni, Cu) was synthesized by melt-spinning. The change of transition element M in these Gd-based metallic glasses was proven to induce huge variations of the Curie temperature TC, magnetic entropy change peak values ΔSm<sup>peak</sup>, and widths at half maximum values of the magnetic entropy change δT. When M is non magnetic (M = Co, Ni, Cu), the samples behave similarly: they display high values of ΔSm<sup>peak</sup> (between -6.6 and -8.2 J/kg K in a magnetic field variation of 4.6 T), average δT values (between 77 and 120 K) and no magnetic hysteresis. On the contrary, when M carries a magnetic moment (M = Mn), some irreversibility appears at low temperature, ΔSm<sup>peak</sup> is lower (only 3.1 J/kg K for μ0H = 4.6 T) and the magnetic transition is very large (δT = 199 K for μ0H = 4.6 T). These features are explained by some antiparallel coupling between Mn atoms randomly located in the metallic glass. This leads to the occurrence of a cluster-glass behavior at low temperature (35 K), following the ferromagnetic transition observed at 180 K when the temperature is decreased. Also, power law fittings of ΔSm<sup>peak</sup> and δT versus μ0H were performed and show that δT is less field dependent than ΔSm<sup>peak</sup>. We could then identify an interesting way of improving the refrigeration capacity of the material at low magnetic field.Read less <
English Keywords
Nickel alloys
Curie temperature
Cobalt alloys
Copper alloys
Entropy
Gadolinium alloys
Indium alloys
Magnetic transitions
Magnetocaloric effects
Manganese alloys
Melt spinning
Origin
Hal imported