Near-critical fluid boiling: overheating and wetting films
GARRABOS, Yves
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
GARRABOS, Yves
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
LECOUTRE-CHABOT, Carole
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
< Leer menos
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
ESEME : Équipe du Supercritique pour l'Environnement, les Matériaux et l'Espace : Équipe commune CEA-CNRS (2000-2014)
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en
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Este ítem está publicado en
European Physical Journal E: Soft matter and biological physics. 2008, vol. 26, n° 4, p. 345-353
EDP Sciences: EPJ
Resumen en inglés
The heating of coexisting gas and liquid phases of pure fluid through its critical point makes the fluid extremely compressible, expandable, slows the diffusive transport, and decreases the contact angle to zero (perfect ...Leer más >
The heating of coexisting gas and liquid phases of pure fluid through its critical point makes the fluid extremely compressible, expandable, slows the diffusive transport, and decreases the contact angle to zero (perfect wetting by the liquid phase). We have performed experiments on near-critical fluids in a variable volume cell in the weightlessness of an orbiting space vehicle, to suppress buoyancy-driven flows and gravitational constraints on the liquid-gas interface. The high compressibility, high thermal expansion, and low thermal diffusivity lead to a pronounced adiabatic heating called the piston effect. We have directly visualized the near-critical fluid's boundary layer response to a volume quench when the external temperature is held constant. We have found that when the system's temperature T is increased at a constant rate past the critical temperature T(c), the interior of the fluid gains a higher temperature than the hot wall (overheating). This extends previous results in temperature quenching experiments in a similarly prepared system when the gas is clearly isolated from the wall. Large elliptical wetting film distortions are also seen during these ramps. By ray tracing through the elliptically shaped wetting film, we find very thick wetting film on the walls. This wetting film is at least one order of magnitude thicker than films that form in the Earth's gravity. The thick wetting film isolates the gas bubble from the wall allowing gas overheating to occur due to the difference in the piston effect response between gas and liquid. Remarkably, this overheating continues and actually increases when the fluid is ramped into the single-phase supercritical phase.< Leer menos
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