Controlling thermally induced electron transfer in cyano-bridged molecular squares: from solid state to solution.
LI, Dongfeng
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Leer más >
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
LI, Dongfeng
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
< Leer menos
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Idioma
en
Article de revue
Este ítem está publicado en
Chemistry - A European Journal. 2011, vol. 17, n° 42, p. 11704-11708
Wiley-VCH Verlag
Resumen en inglés
A new cyano-based {Fe<sub>2</sub>Co<sub>2</sub>} complex has been synthesized, and its optical and magnetic properties described in the frame of an intramolecular electron transfer. Due to methyl functionalization of the ...Leer más >
A new cyano-based {Fe<sub>2</sub>Co<sub>2</sub>} complex has been synthesized, and its optical and magnetic properties described in the frame of an intramolecular electron transfer. Due to methyl functionalization of the ligand, which gives good solubility to this complex, its thermally induced switchable behavior has been transferred to solution and finely tuned over a broad temperature range by adjusting the solvent composition and polarity.< Leer menos
Palabras clave
Cyanides
Electron transfer
Magnetic properties
Solvent effects
UV/Vis spectroscopy
Orígen
Importado de HalCentros de investigación